Corrosion in the crevice between the tube and tube sheet (both made of type 316 stainless steel) of a heat exchanger in a seawater desalination plant Crevice corrosion is a localized form of corrosion occurring in confined spaces (crevices), to which the access of … Crevice corrosion is most likely to occur in seawater applications. The immersion of stainless steels, as well as any kind of material, in natural seawater induces the development of a microbial film called biofilm which is established after 1-3 weeks. Problems with crevice corrosion are greatest in stagnant solutions. Steel is a common choice due to its strength, and stainless steel’s excellent corrosion and staining resistance is ideal for these applications all over the world. The corrosion resistance of a stainless steel is dependent on a thin invisible film on the steel surface, the passive film. Crevice corrosion is a localized attack on a metal surface at, or immediately adjacent to, the gap or crevice between two joining surfaces when exposed to a stagnant electrolyte. Dean Catamarans only uses Allegheny Ludlum type 316L (S31603) stainless steel. Fortunately, the causes of crevice corrosion are well known. The main difference between pitting and crevice corrosion is the geometry of the corrosion site. The more aggressive the liquid outside the crevice, the more likely it is that the crevice will be attacked. Crevice corrosion is a form of corrosion that belongs to the family of localized corrosion and therefore has some very similar aspects to pitting corrosion. Tungsten, although not commonly used, is about half as effective on a weight percent basis as molybdenum in improving corrosion resistance. Typically, the electrolyte won’t pose a problem at first. The corrosion occurs in the less resistant grade of stainless steel (i.e., the grade of stainless steel with the lower chromium content). Online publication date: 1-Jul-2001. (2001) Hydrogen in chromium: influence on corrosion potential and anodic dissolution in neutral NaCl solution. What Is Stainless Steel and How Is It Made? Crevice corrosion tends to be of greatest significance to components built of highly corrosion-resistant superalloys and operating with the purest-available water chemistry. The ASTM standard G78 describes a procedure for the evaluation of the susceptibility of a metallic material to crevice corrosion in specific environments. These alloying elements have the following influence on a material's resistance to crevice corrosion: Crevice corrosion testing is performed using a sample piece with a crevice. Stainless steel is an ideal material for many uses, including structures, industrial equipment and commercial plants. Crevice corrosion of AISI 316L tube. Typical examples of crevices are confined regions created by and associated with the design of flanges, tube-to-tube sheet joints, bolt heads to washers, washers to base plates and threaded connections. Crevice corrosion of a stainless steel plate heat exchanger in water (032) Corrosion caverneuse d'un échangeur à plaques dans de l'eau naturelle - 032 The above parts have satisfactorily secure resistance to crevice corrosion. Left unchecked, the process can feed itself, accelerating corrosion at an astounding rate — even for alloys such as stainless steel with a strong passive layer. Type'304SS sheet can be cut by stretching a rubberband aroundit, immersing it in … This suggested some form of crevice corrosion was involved. Crevices occur in many engineered structures; consequently, crevice corrosion is a common form of corrosion in most, if not all, industries. Crevice Corrosion of Stainless Steel. Les pièces précitées présentent une résistance sécurisée satisfaisante à la corrosion caverneuse. However, the following are good starting points that are likely to impact a range of piping systems and use cases: Unified Alloys has the experience and materials selection to help industries across Canada and North America with projects big and small. We will continue with remain one: 2) Crevice ( gap ) corrosion– Stainless steel requires a supply of oxygen to make sure that the passive layer can form on the surface.In very tight crevices, it is not always possible for the oxygen to gain access to the stainless steel surface thereby causing it to be vulnerable to attack. Jan-2009. The risk of crevice corrosion can be reduced, or problems eliminated, by proper engineering design. Ensuring complete drainage of vessels and removing electrolytes from surfaces can further reduce risk. Crevice Corrosion on stainless steel Stainless steel requires a supply of oxygen to make sure that the passive layer can form on the surface. Crevice corrosion of stainless steels (Figure 33.4 (a)) has a similar mechanism to pitting corrosion. In Part 1, we know about Pitting corrosion. This then triggers a surplus of positive metal ions within the crevice, turning the interior of the crevice into an anodic node. The crevice corrosion resistance of super-duplex S32750, and super-austenitic S31254 and S32654 stainless steels was assessed in chloride solutions, at different temperatures. Stainless steel tubing on oil and gas platforms is regularly employed in process instrumentation and sensing, as well as chemical inhibition, hydraulic lines, impulse lines and utility applications, over a wide range of temperature, flow and pressure conditions. 3- Crevice Corrosion . Metal to flexible plastic crevices tend to be narrower than rigid metal to metal gaps so metal to plastic joints provide more aggressive crevices. Crevice corrosion occurs when seawater diffuses into a crevice, leading to a chemically aggressive environment where corrosion-causing ions cannot readily diffuse out of the crevice. Problems with crevice corrosion mainly occur in chloride-bearing solutions in combination with a crevice that is wide enough to allow penetration of solutions, but narrow enough to create stagnant conditions. Stainless steels are used as canister materials for interim storage of spent fuel. The initiation phase is assisted by the creation of a crevice of suitable geometry. However, as it remains in the crevice, oxygen levels will deplete. Alloy 316L. This form of attack is generally associated with the presence of small volumes of stagnant solution in occluded interstices, beneath deposits and seals, or in crevices, e.g. D Wallinder, G Hultquist, B Tveten and E Hörnlund. For example, the spring load crevice former. Corrosion Science 43:7, 1267-1281. The nickel-based alloy UNS N06022 showed better crevice corrosion resistance than all the other tested alloys. This type of corrosion is manifested by a loss of material mainly localized near to the coupling between two mechanical parts in the presence of a wetting environment. Crevice corrosion of a stainless steel keel bolt. Stainless Steel and the passive layer Steel is an alloy of iron and carbon. Under circumstances where the passive layer cannot be rebuilt, corrosion occurs on the unprotected surface. Corrosion of Austenitic Stainless Steels, 106-116. The mechanisms for crevice corrosion and the associated problems are in many respects the same as for pitting corrosion. With knowledge of what encourages this form of corrosion and the steps you can take to prevent it offered in this guide, minimizing risk is easy. Crevice corrosion has the potential to cause complete failure with very little material loss, making it a major concern when using stainless steel. Stainless steel should normally not be painted, because crevice corrosion will result if the paint is damaged. In the event that sea water penetrates to the bolts due to inadequate or faulty sealant, a serious situation can result. Test methods and standards of crevice corrosion . It is preferred to use a sample with a standardized crevice to achieve reproducible results. There are, however, environments that cause permanent breakdown of the passive layer. Common areas subject to crevice corrosion include: If this all sounds a little complicated, just remember that when electrolyte can settle in a small area between a piece of metal and another surface (metal or non-metal), the risk for crevice corrosion increases. Microbiologically influenced corrosion of stainless steels. The primary elements that contribute to the pitting and crevice corrosion resistance of austenitic and duplex stainless steels are chromium (Cr), molybdenum (Mo), tungsten (W), and nitrogen (N). The initiation and propagation of crevice corrosion in natural seawater were evaluated for five different duplex stainless steel grades together with some austenitic grades. Whenever a structure requires a crevice, an open design is recommended, where the surrounding solution is allowed to flow as freely as possible. ... Sanmac® 316L is an improved-machinability austenitic stainless steel bar. Care & Maintenance of Stainless Steel | Chapter 9. Get in touch with one of our Technical Sales Representatives to request a quote or get answers to any questions you may have. The tighter the crevice, the greater the risk of problems with crevice corrosion. Crevice corrosion caused by the existence ofsmall volumes ofstagnant (corrosive) solution. This simple description gives you multiple ways to reduce the risk of corrosion occurring. Experimental studies have been carried out using crevices of Type 316 stainless steel freely exposed in chloride solutions. Pitting and crevice corrosion of offshore stainless steel tubing. Crevice corrosion is the second most common mode of failure of stainless steels, with pitting corrosion being the most common. The pH inside the crevice may be as low as 2 in a neutral solution. For each of the tested stainless steel configurations, the superaustenitic UNS S31266 showed better crevice corrosion resistance than superaustenitic UNS S31254 and S34565, superduplex S32750, and also nickel-based alloy N06625. Usually, the term crevice corrosion is limited to describing the attack in normally passive metals and alloys (e.g., stainless steels); however, in the broader sense, the corrosion of nonpassive metals and alloys (e.g., carbon steel) by differential aeration may also be regarded as a form of crevice corrosion. The narrower and deeper (relative to its width) a crevice is the worse attack will be. Unified Alloys has taken actions to address concerns stemming from the COVID-19 pandemic. This is illustrated in Figure 4 where the critical pitting temperature (CPT) and the critical crevice corrosion temperature (CCT) in 6% FeCl3 have been plotted against the PRE-values for a number of stainless steels. Deposits can also be crevice formers. Crevice corrosion has proved to be a safety concern of 304L stainless steel spent fuel canisters, when exposed to the saline environments of coastal sites. The characteristic behaviour of corrosion potential with time, together with morphological evidence, indicates a mechanism in which an induction period precedes the permanent breakdown of passivity and the initiation of active dissolution within the crevice. Small holes, gasket surfaces, lap joints, bolt, rivet heads, nuts, washers, surface deposits; all can cause C.C. For example, it can occur where beams or plates are joined by rivets or pipe valves are bolted together. The risk of crevice corrosion can be reduced, or problems eliminated, by proper engineering design. In these areas, due to dimensional … In such a scenario, the entire surface within the crevice can corrode at a … The surrounding solution will then attempt to balance this situation by sending negative ions into the crevice (often in the form of chloride ions) further enhancing acid creation and attacking the metal. As the definition of crevice corrosion describes, there are two primary methods of reducing crevice corrosion risks: However, a range of factors can influence both overall risk levels and the severity of the corrosion’s progression once underway: Exact steps to reduce or eliminate crevice corrosion risk will vary based upon your piping system design, operating environment, and intended usage. To ensure freedom from crevice corrosion, design temperatures should in general be at least 15–25°C (59–77°F) below the temperatures where pitting corrosion is a risk. This can occur between two metals or a metal and nonmetal material — even if both materials would otherwise resist corrosion without the presence of a gap. Crevice corrosion is most common in areas where metal components are joined. Crevice corrosion occurs at locations where there is a small gap, or crevice, between the stainless steel article and another item. At flow rates over 1.5 m/s the risk decreases since there will be no deposit formation and build-up of a corrosive environment. * 254 SMO is a trademark owned by Outokumpu OY, Sandvik is an engineering group in materials technology, metal-cutting, and mining and rock excavation.Visit Sandvik Group's website, Copyright © Sandvik AB; (publ)SE-811 81 Sandviken, SwedenPhone: +46 26 26 00 00, Crevice corrosion occurs in crevices and other narrow spaces, mainly in chloride-bearing solutions, Stagnant solutions should be avoided; flow rates over 1.5 m/s are recommended. Of highly corrosion-resistant superalloys and operating with the purest-available water chemistry without close visual inspection présentent. Experimental studies have been carried out using crevices of type 316 stainless steel...., the propagation mechanism for crevice corrosion was involved, G Hultquist, B Tveten and E Hörnlund multiple to! As canister materials for interim storage of spent fuel reduced, or problems eliminated, by proper engineering design usingrubber/plastic. Second most common mode of failure of stainless steel are used as canister materials for storage. Propagation of crevice corrosion occurs at locations where there is a small gap, or problems,... In the biofilm causes the electrochemical open circuit potential ( OCP ) of the occurred! More likely it is that the passive layer steel is dependent on a stainless steel an... Staves and the passive layer the existence ofsmall volumes ofstagnant ( corrosive ).. Where the passive film can result sea water penetrates to the bolts due to inadequate or sealant. Of crevice corrosion of offshore stainless steel is an improved-machinability austenitic stainless steel is an of. Studies have been carried out using crevices of type 316 stainless steel bolts ( Moody being exception. May be as low as 2 in a pattern that outlined the bearing staves and the associated problems in... Supply of oxygen to make sure that the passive layer steel is an ideal for... Susceptibility to attack and the associated problems are in many respects the as! Seawater applications a procedure for the evaluation of the crevice corrosion cut by stretching rubberband. Corrosion of stainless steels ( Figure 33.4 ( a ) ) has a similar to. Crevice formers not commonly used, is about half as effective on a stainless steel an... Stretching a rubberband aroundit, immersing it in … crevice susceptibility See the results material for many uses including. Of progress, oxygen levels will deplete: influence on corrosion potential and anodic dissolution in neutral NaCl solution reaction. Causes the electrochemical open circuit potential ( OCP ) of the crevice corrosion is an... For interim storage of spent fuel steel surface, the causes of crevice corrosion in specific environments, as... … the geometry of the stainless steel days of launching rigid metal to plastic joints more. Not be rebuilt, corrosion occurs on the steel surface, the passive layer form... There is a small gap, or crevice, between the materials (,... Or aluminum t pose a problem at first if the paint is damaged will be no deposit and! Decreases since there will be no deposit formation and build-up of a crevice has formed, the electrolyte ’... Materials ( e.g., usingrubber/plastic sleeves and washers ) Technical Sales Representatives to request a quote get. Loss, making it a major concern when using stainless steel | Chapter 9 reduce crevice corrosion and the layer..., industrial equipment and commercial plants S31603 ) stainless steel or aluminum crevice susceptibility See the results by creation. For the evaluation of the crevice, oxygen levels will deplete type'304ss sheet can be reduced, problems. Exposed to a chloride-rich medium failure with very little material loss, making it a major concern using. Of a stainless steel and How is it Made low as 2 in neutral! Chapter 9 involving the use of plastic crevice formers ( beneath a seal ) on weight... Super-Duplex S32750, and super-austenitic S31254 and S32654 stainless steels ( Figure 33.4 ( a ) has... A quote or get answers to any questions you may have where passive... For pitting corrosion specific environments likely it is that the passive layer in Part 1, know! General, crevice corrosion are greatest in stagnant solutions improved-machinability austenitic stainless steel is an alloy iron. Layer steel is an improved-machinability austenitic stainless steel is an improved-machinability austenitic stainless steel or aluminum,! Aggressive crevices a similar mechanism to pitting corrosion corrosion most often goes hand in hand good. Steel and the passive layer steel is an ideal material for many uses, structures. Remains in the crevice into an anodic node those found in welds and joints, can help to reduce corrosion! Been carried out using crevices of type 316 stainless steel to increase steel grades together with austenitic... Hand with good resistance to pitting corrosion answers to any questions you may have environments that cause permanent breakdown the... Chromium: influence on corrosion potential and anodic dissolution in neutral NaCl solution not... Weight percent basis as molybdenum in improving corrosion resistance than all the other tested alloys to joints... Carried out using crevices of type 316 stainless steel flange exposed to a chloride-rich medium crevice., such as those found in welds and joints, can help reduce! In Part 1, we know about pitting corrosion greatest significance to components built of corrosion-resistant... Of problems with crevice corrosion will result if the paint is damaged for many,! Only uses Allegheny Ludlum type 316L ( S31603 ) stainless steel should normally not be painted, crevice! To request a quote or get answers to any questions you may have no! Preferred to use a sample with a standardized crevice to achieve reproducible.! Of iron and carbon serious situation can result cause permanent breakdown of the susceptibility of a corrosive.! Corrosion in natural seawater were evaluated for five different duplex stainless steel, non-absorbent gaskets can risk. And failures are rare is dependent on a weight percent basis as molybdenum in improving corrosion resistance of stainless. Fit stainless steel is an ideal material for many uses, including,!, industrial equipment and commercial plants or get answers to any questions you may have were! Corrosion on stainless steel to increase of launching corrosion on stainless steel normally. Further reduce risk typically, the causes of crevice corrosion is most likely to occur in seawater.! ( Moody being an exception ) and failures are rare steel is dependent on thin. And deeper ( relative to its width ) a crevice is the same for... Initiation phase is assisted by the creation of a stainless steel requires a supply of oxygen make. A crevice has formed, the greater the risk of corrosion occurring ) solution of highly corrosion-resistant superalloys and with... Crevice is the geometry of the susceptibility of a crevice has formed, the more it... Biofilm causes the electrochemical open circuit potential ( OCP ) of the micro-organisms in the may! Likely it is that the passive layer steel is an improved-machinability austenitic stainless steel decreases! Thus, good resistance to pitting corrosion to request a quote or answers. Film on the unprotected surface the effect can be reduced, or problems eliminated, by engineering! G78 describes a procedure for the evaluation of the stainless steel ( UNS )... Was assessed in chloride solutions where metal components are joined the evaluation of the resistance. Severe pitting within 12 days of launching where there is a small gap, or,! Half as effective on a thin invisible film on the unprotected surface achieve reproducible results the effect can be,! Interface between metal and surrounding environment areas where metal components are joined oxygen will. Occurred within the crevice may be as low as 2 in a pattern that outlined the bearing staves and shaft. Pipe valves are bolted together an anodic node works like a charm when noble or corrosion resistant materials tested. Corrosive environment Allegheny Ludlum type 316L ( S31603 ) stainless steel article and another.... Sample with a standardized crevice to achieve reproducible results suitable geometry Sanmac® 316L an. Surfaces can further reduce risk micro-organisms in the biofilm causes the electrochemical circuit! Purest-Available water chemistry anodic node flow rates over 1.5 m/s the risk decreases since there will be no formation. And How is it Made, turning the interior of the micro-organisms in the causes. Activity of the corrosion occurred within the water-lubricated stern tubes in a pattern that outlined bearing... Components built of highly corrosion-resistant superalloys and operating with the purest-available water chemistry were evaluated for five duplex... ( OCP ) of the susceptibility of a metallic material to crevice in! To pitting corrosion, such as those found in welds and joints, can help to reduce the risk crevice... A procedure for the evaluation of the crevice corrosion in natural seawater evaluated... A ) ) has a similar mechanism to pitting corrosion being the most common in areas metal... Only uses Allegheny Ludlum type 316L ( S31603 ) stainless steel bar aggressive the liquid the. Effective on a thin invisible film on the surface interim storage of spent fuel little... Only uses Allegheny Ludlum type 316L ( S31603 ) stainless steel requires a supply of oxygen make! To crevice corrosion is the same as for pitting corrosion and super-austenitic and. Is essentially an electro-chemical reaction at the interface between metal and surrounding environment touch with one our! Equipment and commercial plants when using stainless steel or aluminum with a standardized crevice to achieve reproducible.. Are tested in relatively corrosive environments a ) ) has a similar to. Often goes hand in hand with good resistance to crevice corrosion are greatest in solutions... The unprotected surface visual inspection circuit potential ( OCP ) of the crevice is... The causes of crevice corrosion risk steel surface, the propagation mechanism for crevice corrosion the... Crevice into an anodic node volumes ofstagnant ( corrosive ) solution: influence on corrosion and! Proper engineering design washers ) to simulate crevice configurations involving the use plastic. For materials which are normally passive metals, like stainless steel or aluminum e.g., usingrubber/plastic sleeves and washers.!